Pulse Reverse Protocol for efficient suppression of dendritic micro-structures in rechargeable batteries
نویسندگان
چکیده
The ramified and stochastic evolution of dendritic microstructures has been a major issue on the safety longevity rechargeable batteries, particularly for utilization metallic electrodes. We computationally develop pulse-reverse protocols effective halting growing during extensive charging periods far beyond inter-ionic collisions. Our framework is based competitiveness growth pulse period versus dissolution (sub)branches reverse charge. detachment atoms from structure preferentially occurs meta-stable sites which possess lowest coordination number require activation energy dissolution. prove that even an infinitesimal charge more than extended pulse-relaxation method suppression structures.
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ژورنال
عنوان ژورنال: Electrochimica Acta
سال: 2021
ISSN: ['1873-3859', '0013-4686']
DOI: https://doi.org/10.1016/j.electacta.2020.137469